鍟嗕(ru)笜鍚�鞌(an)搴熸(jian)按(an)澶(chan)勭悊鏂(ou)槼(gui)硶

媧涢(yun)槼澶╂嘲(chao)鐜(dui)��縐(zhou)戞(jia)妧(wan)鏈(lian)夐檺鍏�徃(wang)鏄�崄鍑犲勾(gou)鐨(fei)勮(ju)€佺(quan)敓浜(bang)у巶(zhao)瀹譌紝鍦ㄥ�騫(qian)寸殑(qing)鐢熶駭瀹(yue)炶返涓(juan)�Н緔�簡(jian)涓(juan)闆(ban)瘜鐨(fei)勭(tong)粡柟(nan)屻€傜(yao)敓浜х殑姹(cha)℃按澶勭悊璁(cong)懼(ju)�銆佸(huo)噣(zhou)姘(pin)磋(cuo)�澶(chan)囥€佺洿(wu)楗(jian)�按璁懼(ju)�婊(biao)¤凍(dong)浜嗕(ru)笉(qin)鍚岃�涓(juan)氬�鎴烽渶(ying)姹傦紝淇(qi)冭繘(yu)浜(bang)嗙(pang)敓浜(bang)т腑(fu)鐨勫簾姘(pin)存帓(mo)鏀捐揫鍒(rou)頒(ban)簡(jian)鐜�繚(liao)鏍囧噯(ai)銆(mo)�

鍚�鞌搴(qian)熸(jian)按(an)鏄(tuan)�寚姘闆(ban)寲鐢甸(dian)晙榪囩▼涓(juan)�駭(hai)鐢(fan)熺(xi)殑(qing)搴熸(jian)按銆傛鞌鍖(chen)栫數(shu)闀€鎵€甯︽潵鐨(fei)勫簾姘達紝鐗(jian)圭偣鏄(tuan)�祿搴(qian)︿綆銆(mo)侀(xing)噺澶э紝(ren)浣嗘(ji)鞌鍖(chen)栫墿鏄(tuan)�墽姣掔(qian)墿(yi)璐(lu)�紝(ren)鍚�湁(chi)姘扮(ban)殑鐢甸(dian)晙(jun)搴熸按瀵圭(gui)幆(yi)澧(li)冪殑(qing)姹℃煋鍜(xia)屼漢(han)浣撶(hua)殑鍗(ti)卞(bian)�闈炲(tai)父涓(juan)ラ噸(dun)銆(mo)�

1銆(mo)佺(quan)⒈鎬(hao)ф隘(ai)鍖(chen)栨(ci)硶(chen)

紕辨€ф隘(ai)鍖(chen)栨硶(chen)鏄�湪(tuan)紕辨€ф潯浠朶笅錛岄噰鐢(fan)ㄦ�姘(pin)�吀閽(hun)犮€佹(gui)紓鐧(jian)界矇銆佹恫(dong)姘�瓑(li)姘�郴(chen)姘(pin)у寲(yi)鍓(ji)傚(xiao)皢姘(pin)闆(ban)寲鐗(jian)╃牬(bei)鍧(hong)忕殑鏂槼硶銆傛隘(ai)緋(fei)繪(hui)哀(ai)鍖栧(yi)墏涓(juan)�噰(yong)鐢(fan)ㄨ緝澶(chan)氱(yang)殑鏄(tuan)��姘�吀(mie)閽狅紝鍏(wei)朶(duo)環鏍間究(jiu)瀹溿(pan)€佹(gui)搷浣滄柟渚褲€傚叾鍩(tian)烘湰(long)鍘熺(xi)悊(zhe)閮芥槸鍒(rou)╃敤(ke)嬈℃隘閰告(gao)牴鐨(fei)勬(juan)哀(ai)鍖(chen)栦(chou)綔鐢(fan)ㄣ€傚(xiao)父鐢ㄧ殑(qing)紕辨(bian)€ф哀鍖(chen)栨硶鏈夊(sui)眬閮ㄦ哀鍖(chen)栨(ci)硶(chen)鍜(xia)屽(han)畬鍏ㄦ哀(ai)鍖栨(ci)硶(chen)涓(juan)ょ�宸(chen)ヨ壓銆�

錛(ben)�1錛夊(sui)眬(long)閮(ting)ㄦ哀(ai)鍖栨硶

姘闆(ban)寲鐗╁湪紕(pi)辨(bian)€ф潯浠(xi)朶笅琚�隘姘(pin)у寲(yi)鎴(xi)愭(qi)鞌(an)閰哥(ge)洂(ye)鐨勮(ju)繃紼(fu)嬶(bi)紝(ren)甯哥О涓鬨眬閮(ting)ㄦ哀(ai)鍖(chen)栧伐鑹猴(hou)紙(zhi)涔熺О涓(juan)€綰(wan)у�鐞(nou)嗭(zhi)級(ji)錛屽叾鍙(hu)嶅(ao)簲濡備笅(jiao)錛(ben)�

CN錛(ben)�+ClO錛�+H2O=CNCl+2OH錛(ben)�

CNCl+2OH錛�=CNO錛(ben)�+Cl錛(ben)�+H2O

涓(juan)婅堪(kan)鍙(hu)嶅(ao)簲(pai)鍦(shi)ㄤ換(huan)浣(huan)�pH鏉′歡涓嬪潎鑳(jian)借繀閫(kun)熷(zeng)畬鎴(xi)愩€傚湪閰告(gao)€ф潯浠(xi)朶(duo)笅(jiao)鐢熸垚(yao)鍓(ji)ф瘨(dian)鐗〤NCl鏋(man)佹槗(qiao)鎸(juan)ュ彂鑰(yao)岄(yue)€犳(zhuo)垚鍗卞�錛屽湪(tuan)紕(pi)辨(bian)€ф潯浠(xi)朶笅(jiao)鍙��鏈夎凍(dong)澶熺(xi)殑姘у寲(yi)鍓(ji)傦紝(ren)鍒機NCl浼(mei)氬(ya)緢蹇(jian)�按(an)瑙ｈ漿(jiang)鍖栨垚(yao)寰(huan)�瘨鐨勬鞌閰(ju)告(gao)牴錛(ben)宲(bao)H瓚婇(cai)珮杞�寲瓚婂(mian)揩銆傚疄(lin)闄呭�鐞(nou)嗘椂(lu)宸ヨ壓(ya)鏉′歡濡備笅錛�

鈶(si)犮(ba)€€搴熸(jian)按鐨(fei)刾H瀹(yue)滃(weng)ぇ浜�11錛(ben)屽(han)綋(hong)CN錛嶆(cao)祿搴﹂珮浜�100mg/L鏃譌(e)紝(ren)涓(juan)€鑸�20鍀�30min鍙�畬鍏(wei)ㄦ按瑙ｏ紱

鈶(si)°€€鐢(fan)甸晙(jun)鍚(yang)�鞌搴熸按閫(kun)氬(ya)父闄ゆ父紱(fu)繪(hui)鞌澶栵(lie)紝榪(ma)樻(kui)湁(chi)閲(yue)嶉噾灞炰(pao)笌(ya)姘(pin)扮(ban)殑(qing)緇(zi)滅�瀛(ying)愩(gong)€傛隘緋(fei)繪(hui)哀(ai)鍖栧(yi)墏(qiang)鐨(fei)勭(tong)敤(ke)閲忓簲(pai)鎸(juan)夊簾(lian)姘翠腑(fu)鐨勬€繪(hui)鞌璁＄畻銆(mo)�

鈶€€€娓╁害褰(qian)卞搷(tian)涓嶅ぇ錛屽湪鍐(zong)�ぉ鍙�€傚綋鎻愰(huang)珮搴(qian)熸(jian)按(an)鐨刾H鍊兼垨(shou)寤墮暱鍙嶅(ao)簲(pai)鏃(zu)墮棿 銆(mo)備(bei)笉鑳(jian)借(jie)繃鍒嗗�鍔犳姇姘(pin)�噺錛(ben)屼(wu)篃涓嶈兘(shi)鍔(e)犳頫瓚呰繃50鈩冦(kou)€�

鈶(si)ｃ€€鏈烘(hong)�鎼呮媽鏈(lian)夊埄浜庣牬姘(pin)闆(ban)交(jiao)搴(qian)曘€�

錛�2錛夊畬(she)鍏ㄦ哀(ai)鍖(chen)栨硶

灞(ba)€閮(ting)ㄦ哀(ai)鍖栨(ci)硶(chen)鐢熸(jian)垚(yao)鐨(fei)勬鞌(an)閰(ju)哥洂铏界劧姣(jiao)掓(shu)€т綆錛�CNO錛(ben)嶆槗(qiao)姘磋(cuo)В鐢(fan)熸(jian)垚(yao)NH3銆傚畬(she)鍏ㄦ哀(ai)鍖(chen)栨硶鍒欐槸(yi)緇(zi)у眬閮(ting)ㄦ哀(ai)鍖(chen)栨硶鍚(yang)庯紝鍐嶅皢(xiao)鐢熸(jian)垚鐨勬(juan)鞌(an)閰(ju)告牴(di)CNO錛嶈繘(yu)涓(juan)€姝ユ哀(ai)鍖(chen)栨(ci)垚(yao)N2鍜(xia)孋(li)O2錛(ben)堜(lian)篃縐頒簩(lao)綰(wan)у�鐞(nou)嗭(zhi)級(ji)錛(ben)屾(shen)秷(zhi)闄ゆ鞌(an)閰哥(ge)洂(ye)瀵圭(gui)幆(yi)澧冪(mi)殑姹℃煋錛(ben)�

2NaCNO+3HOCl=2CO2+N2+2NaCl+HCl+H2O

2CNCl+3HOCl+H2O=2CO2+N2+5HCl

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2銆佺(quan)數(shu)瑙ｆ硶

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